Pyridinium trans-diaquabis[oxalato(2−)-κ2O1,O2]chromate(III) urea monosolvate

Autor: Gouet Bebga, Martin Signé, Justin Nenwa, Mohammed Mbarki, Boniface P. T. Fokwa
Jazyk: angličtina
Rok vydání: 2013
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 69, Iss 10, Pp m567-m567 (2013)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536813026135
Popis: The asymmetric unit of the title solvated molecular salt, (C5H6N)[Cr(C2O4)2(H2O)2]·CO(NH2)2, contains half a formula unit. Each component is completed by crystallographic twofold symmetry: in the cation, one C and the N atom lie on the rotation axis; in the anion, the CrIII ion lies on the axis; in the solvent molecule, the C and the O atom lie on the axis. The aqua ligands are in a trans disposition in the resulting CrO6 octahedron. In the crystal, the components are linked by O—H...O, N—H...O and N—H...(O,O) hydrogen bonds, generating a three-dimensional network.
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