Pd(II)-Catalyzed C-H Acylation of (Hetero)arenes—Recent Advances

Autor:	Carlos Santiago, Nuria Sotomayor, Esther Lete
Jazyk:	angličtina
Rok vydání:	2020
Předmět:	C-H activation acylation palladium arenes heteroarenes Organic chemistry QD241-441
Zdroj:	Molecules, Vol 25, Iss 14, p 3247 (2020)
Druh dokumentu:	article
ISSN:	25143247 1420-3049
DOI:	10.3390/molecules25143247
Popis:	Di(hetero)aryl ketones are important motifs present in natural products, pharmaceuticals or agrochemicals. In recent years, Pd(II)-catalyzed acylation of (hetero)arenes in the presence of an oxidant has emerged as a catalytic alternative to classical acylation methods, reducing the production of toxic metal waste. Different directing groups and acyl sources are being studied for this purpose, although further development is required to face mainly selectivity problems in order to be applied in the synthesis of more complex molecules. Selected recent developments and applications are covered in this review.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/a72f17c41f3b48238c0483dffcde7386 Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.