| Autor: |
Junxia Yuan, Xiaofei Li, Feifan Wu, Cheng Pan, Haitao Yang |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
BioResources, Vol 19, Iss 3, Pp 4886-4898 (2024) |
| Druh dokumentu: |
article |
| ISSN: |
1930-2126 |
| Popis: |
Using renewable steam-exploded poplar (SEP) as carbon source, nickel metal doped carbon hybrid materials were designed to synthesize catalysts (Ni/SEP) with certain oxygen evolution reaction (OER) properties and were compared with nickel catalysts supported on metal organic framework structure (ZIF67-Ni). The roles of SEP support in Ni-based catalyst were considered. Scanning electron microscope (SEM) images confirmed that the fiber could better hinder the aggregation of metal particles. Fourier transform infrared spectroscopy (FT-IR) indicated the presence of surface OH groups after the reduction process. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses confirmed the major form of metallic Ni in the resulting Ni catalysts. Carbon materials as carriers, the synergetic effect of Ni-doped, and carbon carrier played an important role in facilitating the kinetics of OER, which was similar to the carrier of metal-organic frame material. Notably, the Ni/SEP (11.3 mF/cm-2) and ZIF67-Ni (37.2 mF/cm-2) with better OER performance exhibited a smaller double layer capacitances (Cdl), suggesting the intrinsic OER catalytic activity of the Ni/SEP and ZIF67-Ni were much higher in comparison to the ZIF67-Ni/SEP. Moreover, the inferior performance of Ni/SEP further indicated that the synergistic effect between carbon and Ni/NiO contributes to the enhanced OER activity. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
|
