Cycloaddition of natural epoxide and CO2 with the help of multi-nuclear phthalocyanine complexes attached to FPS as a nanosaramic

Autor: Amin Fallah Koushki, Seyed Mojtaba Movahedifar, Amin Honarbakhsh, Mehdi Nobahari, Rahele Zhiani
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Journal of CO2 Utilization, Vol 85, Iss , Pp 102885- (2024)
Druh dokumentu: article
ISSN: 2212-9839
DOI: 10.1016/j.jcou.2024.102885
Popis: This study introduces a three-dimensional, densely packed amide polyphthalocyaninezinc, supported by fibrous phosphosilicate (FPS), for the first time (referred to as Complex@Zn-IL/FPS). The XPS and EDX images confirmed that the Complex@Zn-IL nanosaramic was evenly distributed on the FPS’s surface. The cycloaddition reaction from CO2 and natural epoxide using Complex@Zn-IL/FPS nanosaramic as catalysts was reported. Furthermore, the catalyst’s structural heterogeneity was examined using various methods, including SEM, FT-IR, XPS, TEM, and TGA. There was no evidence of zinc leaching into the fluid. In addition, hot filtration provided a comprehensive understanding of the catalyst’s heterogeneous nature. The catalyst’s practical and straightforward reusability was noted after the reaction was completed.
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