1-Ethyl-3-methyl-1H-imidazol-3-ium spiropentaborate
| Autor: | T. Gannon Parker, Divya Pubbi, Austin Beehler, Thomas E. Albrecht-Schmitt |
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| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 2, Pp o171-o172 (2014) |
| Druh dokumentu: | article |
| ISSN: | 1600-5368 16005368 |
| DOI: | 10.1107/S1600536813034363 |
| Popis: | In the anion of the title compound, (C6H11N2)[B5O6(OH)4], both six-membered borate rings adopt a flattened boat conformation with the spiro-B atom and its opposite O atom deviating from the remainders of the rings by 0.261 (3)/0.101 (2) and 0.160 (3)/0.109 (2) Å, respectively. The imidazolium cation also deviates from planarity due to rotation of the ethyl group (as indicated by the C—N—C—C torsion angle) by 71.4 (2)° out of the plane of the heterocycle. In the crystal, the anions are connected in a three-dimensional network through O—H...O hydrogen bonds, forming channels along the a-axis direction. The cations are situated in the channels, forming C—H...O hydrogen bonds with the anions. |
| Databáze: | Directory of Open Access Journals |
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