Photocatalytic activity of ceramic tiles coated with titania supported on kaolinite

Autor: Talita da Silva Dassoler, Eloise de Sousa Cordeiro, Dachamir Hotza, Agenor De Noni Junior
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Open Ceramics, Vol 13, Iss , Pp 100331- (2023)
Druh dokumentu: article
ISSN: 2666-5395
DOI: 10.1016/j.oceram.2023.100331
Popis: Titania is an established photocatalytic material. The dispersion of titania nanoparticles on kaolinite particles as carrier and support precursor, TiO2-kao, has been studied to avoid losses in photocatalytic efficiency once fired by single-fired porcelain tile route. The photocatalyst was prepared using the hydrolytic sol-gel route. A commercial titania, P25, was used as a reference TiO2. The samples were fast fired at 800, 1015, 1100, and 1185 °C. Degradation of methylene blue was used to assess the photocatalytic performance. TiO2-kao and P25 applied to unglazed plates fired at 800 °C yielded ∼65% degradation, ∼50% due to photocatalysis, and ∼15% due to photolysis. P25 samples retained ∼10% of their photoactivity after firing at 1185 °C, TiO2-kao retained 80%. TiO2-kao on glazed tiles fired at 1185 °C retained 30% photoactivity. The photocatalytic losses in the glazed sample were due to the reduction in contact area caused by particle encapsulation in the glass layer.
Databáze: Directory of Open Access Journals