Mass-spectrometry via oscillatory motion in deep pulsed optical lattices

Autor: Alexandros Gerakis, Mikhail N. Shneider, Peter F. Barker
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Heliyon, Vol 10, Iss 22, Pp e40410- (2024)
Druh dokumentu: article
ISSN: 2405-8440
DOI: 10.1016/j.heliyon.2024.e40410
Popis: We describe a new optical diagnostic for determining the composition of gases by measuring the motion of atoms and molecules trapped within very deep optical lattices. This non-resonant method is analogous to conventional Raman scattering, except that the observed spectral features relate to the oscillatory center-of-mass motion of each species within the lattice, determined uniquely by their respective polarizability-to-mass ratio. Depending on the density of the probed sample, detection occurs either via optical scattering at the high end or via non-resonant ionization at the lower end. We show that such a technique is complementary to conventional mass spectrometry techniques and envision its implementation in existing instruments.
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