Catalyst- and metal-free C(sp 2)–H bond selenylation of (N-hetero)-arenes using diselenides and trichloroisocyanuric acid at room temperature

Autor: José S. S. Neto, Isis J. A. Granja, Marcos R. Scheide, Marcelo S. Franco, Cassio A. O. Moraes, Adilson Beatriz, Dênis P. de Lima, Giancarlo V. Botteselle, Tiago E. A. Frizon, Sumbal Saba, Jamal Rafique, Antonio L. Braga
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Scientific Reports, Vol 13, Iss 1, Pp 1-13 (2023)
Druh dokumentu: article
ISSN: 2045-2322
DOI: 10.1038/s41598-023-41430-9
Popis: Abstract In this paper, we report an eco-friendly approach for the C(sp 2)–H bond selenylation of imidazopyridines and other N-heteroarenes as well as simple arenes at ambient temperature. This new protocol consists of the reaction between (N-hetero)-arenes and the diorganyl-diselenides and trichloroisocyanuric acid (TCCA)-ethanol reagent system. In a short reaction time, the desired selenylated products were obtained regioselectively in good yields, with tolerance for a wide range of functional groups.
Databáze: Directory of Open Access Journals
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