trans-K3[TcO2(CN)4]
| Autor: | Sayandev Chatterjee, Andrew S. Del Negro, Matthew K. Edwards, Brendan Twamley, Jeanette A. Krause, Samuel A. Bryan |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 8, Pp i61-i62 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810028205 |
| Popis: | The structure of the title compound, tripotassium trans-tetracyanidodioxidotechnetate(V), is isotypic with its Re analogue. The [TcO2(CN)4]3− trans-tetracyanidodioxidotechnetate anion has a slightly distorted octahedral configuration. The Tc atom is located on a center of inversion and is bound to two O atoms in axial and to four cyanide ligands in equatorial positions. The Tc—O distance is consistent with a double-bond character. The two potassium cations, one located on a center of inversion and one in a general position, reside in octahedral or tetrahedral environments, respectively. K...O and K...N interactions occur in the 2.7877 (19)–2.8598 (15) Å range. |
| Databáze: | Directory of Open Access Journals |
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