The catalytic activity of different Mn(III) species towards peroxymonosulfate activation for carbamazepine degradation

Autor: Haoxuan Wei, Jujiao Zhao, Md. Hasibur Rahaman, Quanfeng Wang, Jun Zhai
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Catalysis Communications, Vol 173, Iss , Pp 106563- (2023)
Druh dokumentu: article
ISSN: 1873-3905
DOI: 10.1016/j.catcom.2022.106563
Popis: In this study, the catalytic activity of soluble Mn(III) ions, soluble Mn(III)-pyrophosphate (PP), and solid Mn(III) (α-MnO2) towards peroxymonosulfate (PMS) activation was investigated through carbamazepine (CBZ) degradation. The degradation efficiency of CBZ was negligible when soluble Mn(III) ions or Mn(III)-PP were used as catalysts, while 99.7% of CBZ was degraded in the α-MnO2/PMS system with no soluble Mn(III) ions detected. The degradation efficiency of CBZ reduced by 18% with the solid Mn(III) content decreasing. Hence, the solid Mn(III) made the major contribution to PMS activation. This study supported a better understanding of the role of Mn(III) in PMS activation.
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