Polydimethylsiloxane-assisted plasma electrolytic oxidation of Ti for synthesizing SiO2-TiO2 composites for application as Li-ion battery anodes

Autor: Han-Gyoul Gim, Yong-Tae Kim, Jinsub Choi
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Electrochemistry Communications, Vol 148, Iss , Pp 107455- (2023)
Druh dokumentu: article
ISSN: 1388-2481
DOI: 10.1016/j.elecom.2023.107455
Popis: A SiO2-TiO2 composite electrode with the synergistic effects of a stable cycle performance of TiO2 and high theoretical capacity of SiO2 was prepared through the plasma electrolytic oxidation (PEO) of Ti. When a polydimethylsiloxane (PDMS) layer is spin-coated on a Ti substrate (PDMS@Ti), the PEO reaction effectuates immediately on the pristine Ti, where the bubble phase forms first and PEO occurs for an extended period of time at a low voltage. Significantly, compared to the composite film prepared on pristine Ti, the SiO2-TiO2 composite film with a thickness of 80.39 μm exhibits large pores, which are beneficial for facilitating the transportation of Li+ with large amounts of Si. Consequently, a higher areal capacity of 1505.35 μAh cm−2 at a current density of 500 μA cm−2 was achieved compared to that of pristine Ti.
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