Crystal Structures of Furazanes

Autor: Thomas M. Klapötke, Philipp C. Schmid, Jörg Stierstorfer
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: Crystals, Vol 5, Iss 4, Pp 418-432 (2015)
Druh dokumentu: article
ISSN: 2073-4352
DOI: 10.3390/cryst5040418
Popis: Several nitrogen-rich salts of 3-nitramino-4-nitrofurazane and dinitraminoazoxyfurazane were synthesized and characterized by various spectroscopic methods. The crystal structures were determined by low temperature single crystal X-ray diffraction. Moreover the sensitivities toward thermal and mechanical stimuli were determined by differential thermal analysis (DTA) and BAM (Bundesanstalt für Materialforschung und -prüfung) methods. The standard enthalpies of formation were calculated for all compounds at the CBS-4M level of theory, and the energetic performance was predicted with the EXPLO5 V6.02 computer code.
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