The Use of Some Non-conventional Methods in Chemistry of Bicyclohomofarnesenic Methyl Esters

Autor:	Alexandru Ciocarlan, Lidia Lungu, Svetlana Blaja, Ion Dragalin, Aculina Aricu
Jazyk:	angličtina
Rok vydání:	2020
Předmět:	bicyclohomofarnesenic methyl ester microwave irradiation anodic electrooxidation dye-sensitized photooxidation Chemistry QD1-999 General. Including alchemy QD1-65
Zdroj:	Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, Vol 15, Iss 2, Pp 69-77 (2020)
Druh dokumentu:	article
ISSN:	1857-1727 2345-1688
DOI:	10.19261/cjm.2020.791
Popis:	The present paper reports the results of microwave irradiation assisted method for the preparation of bicyclohomofarnesenic methyl esters versus classical Stoll and Hinder method. Moreover, the chemical transformations of bicyclohomofarnesenic methyl esters via anodic electrooxidation and dye-sensitized photooxidation were performed. A new method for the preparation of methyl 7-oxo-13,14,15,16-tetranorlabd-6,8(8)-dien-12-oate and the mechanism of electrochemical products formation are presented. The structure of all synthesized compounds was fully confirmed by spectral methods.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/6fc7630d872f480cbecf06b795d445f0 Zobrazit plný text záznamu View record in DOAJ