| Autor: |
Maryam Afsharpour, Somayeh Darvishi-Farash |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
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| Zdroj: |
Scientific Reports, Vol 13, Iss 1, Pp 1-11 (2023) |
| Druh dokumentu: |
article |
| ISSN: |
2045-2322 |
| DOI: |
10.1038/s41598-023-37170-5 |
| Popis: |
Abstract We developed here the efficient photocatalysts for the removal of high concentrations of tetracycline under visible light by immobilizing the AWO (A = Ag, Bi, Na) nanocrystals on the surface of siligraphene (g-SiC) nanosheets. The g-SiC/AWO composites was synthesized by magnesiothermic synthesis of g-SiC and sonochemical immobilization of tungstates. These new heterojunctions of g-SiC/tungstates show superior photocatalytic activities in the degradation of high concentrations of tetracycline and 97, 98, and 94% of tetracycline were removed by using low amounts of g-SiC/Ag2WO4, g-SiC/Bi2WO6, and g-SiC/Na2WO4 catalysts, respectively. Based on band structures, the band gaps reduce and the photocatalytic activities were extremely enhanced due to the shortening of electron transfer distance through the Z-scheme mechanism. Also, the graphenic structure of g-SiC is another parameter that was effective in improving photocatalytic performance by increasing the electron transfer and decreasing the rate of electron–hole recombination. Furthermore, the π back-bonding of g-SiC with metal atoms increases the electron–hole separation to enhance the photocatalytic activity. Interestingly, g-SiC composites (g-SiC/AWO) showed much higher photocatalytic properties compared to graphene composites (gr/AWO) and can remove the tetracycline even at dark by producing the oxygenated radicals via adsorption of oxygen on the positive charge of Si atoms in siligraphene structure. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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