Photochemical diazidation of alkenes enabled by ligand-to-metal charge transfer and radical ligand transfer

Autor: Kang-Jie Bian, Shih-Chieh Kao, David Nemoto, Xiao-Wei Chen, Julian G. West
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Nature Communications, Vol 13, Iss 1, Pp 1-10 (2022)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-022-35560-3
Popis: The difunctionalization of alkenes allows for efficient construction of molecular complexity. Combining Ligand-to-Metal Charge transfer (LMCT) and Radical Ligand Transfer (RLT), the authors show a photochemical diazidation using iron salts, allowing rapid preparation of vicinal diamines and other privileged synthetic motifs.
Databáze: Directory of Open Access Journals