catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl]

Autor: Hui Li, Qiuping Han, Chenzhong Yao, Qiaojuan Gong, Zhuangwei Wei
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 67, Iss 4, Pp m492-m492 (2011)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536811010671
Popis: In the title compound, [CoCl2(C26H18N4)]n, the CoII atom (site symmetry 2) is tetrahedrally coordinated by two chloride ions and two N atoms from 4,4′-bis(benzimidazol-1-yl)biphenyl ligands: the complete ligand is generated by crystallographic twofold symmetry. The dihedral angle between the benzene rings is 34.67 (8)° and the angle between the benene ring and the adjacent benzimidazole ring system is 43.26 (10)°. The bridging ligand links the CoII atoms into chains propagating in [overline{1}01].
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