Nanostructured Thermoelectric Films Synthesised by Spark Ablation and Their Oxidation Behaviour

Autor: Hendrik Joost van Ginkel, Lisa Mitterhuber, Marijn Willem van de Putte, Mark Huijben, Sten Vollebregt, Guoqi Zhang
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Nanomaterials, Vol 13, Iss 11, p 1778 (2023)
Druh dokumentu: article
ISSN: 2079-4991
DOI: 10.3390/nano13111778
Popis: Reducing the thermal conductivity of thermoelectric materials has been a field of intense research to improve the efficiency of thermoelectric devices. One approach is to create a nanostructured thermoelectric material that has a low thermal conductivity due to its high number of grain boundaries or voids, which scatter phonons. Here, we present a new method based on spark ablation nanoparticle generation to create nanostructured thermoelectric materials, demonstrated using Bi2Te3. The lowest achieved thermal conductivity was −1 K−1 at room temperature with a mean nanoparticle size of 8±2 nm and a porosity of 44%. This is comparable to the best published nanostructured Bi2Te3 films. Oxidation is also shown to be a major issue for nanoporous materials such as the one here, illustrating the importance of immediate, air-tight packaging of such materials after synthesis and deposition.
Databáze: Directory of Open Access Journals