Autor: |
Aigerim Ye. Ayazbayeva, Alexey V. Shakhvorostov, Iskander Sh. Gussenov, Tulegen M. Seilkhanov, Vladimir O. Aseyev, Sarkyt E. Kudaibergenov |
Jazyk: |
angličtina |
Rok vydání: |
2022 |
Předmět: |
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Zdroj: |
Nanomaterials, Vol 12, Iss 14, p 2343 (2022) |
Druh dokumentu: |
article |
ISSN: |
2079-4991 |
DOI: |
10.3390/nano12142343 |
Popis: |
Polyampholyte nanogels based on N-isopropylacrylamide (NIPAM), (3-acrylamidopropyl) trimethylammonium chloride (APTAC) and 2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt (AMPS) were synthesized via conventional redox-initiated free radical copolymerization. The resultant nanogels of various compositions, specifically [NIPAM]:[APTAC]:[AMPS] = 90:5:5; 90:7.5:2.5; 90:2.5:7.5 mol.%, herein abbreviated as NIPAM90-APTAC5-AMPS5, NIPAM90-APTAC7.5-AMPS2.5 and NIPAM90-APTAC2.5-AMPS7.5, were characterized by a combination of 1H NMR and FTIR spectroscopy, TGA, UV–Vis, DLS and zeta potential measurements. The temperature and salt-responsive properties of amphoteric nanogels were studied in aqueous and saline solutions in a temperature range from 25 to 60 °C and at ionic strengths (μ) of 10−3 to 1M NaCl. Volume phase transition temperatures (VPTT) of the charge-balanced nanogel were found to reach a maximum upon the addition of salt, whereas the same parameter for the charge-imbalanced nanogels exhibited a sharp decrease at higher saline concentrations. A wide bimodal distribution of average hydrodynamic sizes of nanogel particles had a tendency to transform to a narrow monomodal peak at elevated temperatures and higher ionic strengths. According to the DLS results, increasing ionic strength results in the clumping of nanogel particles. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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