Bis(2-methoxyanilinium) hexabromidostannate(IV) dihydrate

Autor: Francois Michaud, Slaheddine Kamoun, Sahel Karoui, Hassen Chouaib
Jazyk: angličtina
Rok vydání: 2013
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 69, Iss 12, Pp m678-m679 (2013)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536813031681
Popis: The asymmetric unit of the title compound, (C7H10NO)2[SnBr6]·2H2O, contains one cation, one half-dianion and one lattice water molecule. The [SnBr6]2− dianion, located on an inversion center, exhibits a highly distorted octahedral coordination environment, with Sn—Br bond lengths ranging from 2.2426 (9) to 3.0886 (13) Å. In the crystal, O—H...Br, N—H...Br, N—H...O and C—H...Br hydrogen bonds consolidate the packing, which can be described as consisting of alternating anionic (containing dianions and lattice water molecules) and cationic layers parallel to ab plane.
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