(N-Benzoyl-N-phenylhydroxylaminato)carbonyl(triphenylarsine)rhodium(I)
| Autor: | Mokete A. Motente, Johan Venter, Alice Brink |
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| Jazyk: | angličtina |
| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | IUCrData, Vol 8, Iss 4, p x230355 (2023) |
| Druh dokumentu: | article |
| ISSN: | 2414-3146 24143146 |
| DOI: | 10.1107/S2414314623003553 |
| Popis: | The molecule of the title compound, [Rh(C13H10NO2){As(C6H5)3}(CO)] or [Rh(BPHA)(AsPh3)(CO)] (BPHA is the N-benzoyl-N-phenylhydroxylaminate anion), comprises a bidentate N-benzoyl-N-phenylhydroxylaminate anion coordinating through the O atoms to the soft Lewis acid, rhodium(I), and two monodentate ligands, viz. triphenylarsine and carbonyl. The resulting CO2As coordination environment around the central RhI atom is distorted square planar.= |
| Databáze: | Directory of Open Access Journals |
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