Structural Isomers: Small Change with Big Difference in Anion Storage

Autor:	Huichao Dai, Yuan Chen, Yueyue Cao, Manli Fu, Linnan Guan, Guoqun Zhang, Lei Gong, Mi Tang, Kun Fan, Chengliang Wang
Jazyk:	angličtina
Rok vydání:	2023
Předmět:	Zinc-organic batteries Isomers Solid-state molecular rearrangement Anion storage P-type organic electrode materials Technology
Zdroj:	Nano-Micro Letters, Vol 16, Iss 1, Pp 1-13 (2023)
Druh dokumentu:	article
ISSN:	2311-6706 2150-5551
DOI:	10.1007/s40820-023-01239-7
Popis:	Highlights The effect of small changes in isomers on electrochemical performance have not been focused in batteries and two isomers are reported for Zn-ion batteries here. The isomer tetrathiafulvalene (TTF) could store two monovalent anions reversibly, showing remarkable performance that outperformed most of the reported organic electrode materials for zinc-ion batteries. The isomer tetrathianaphthalene (TTN) could only reversibly store one monovalent anion and upon further oxidation, it would undergo an irreversible solid-state molecular rearrangement to TTF.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/6d4173cb58ad4565bc4830e86459f25a Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
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