Bis{2-ethoxy-6-[2-(methylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(II) nitrate

Autor: Chen-Yi Wang, Zhi-Ping Han, Xiang Wu, Cai-Jun Yuan, Jun-Bo Zhou
Jazyk: angličtina
Rok vydání: 2010
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 66, Iss 2, Pp m120-m120 (2010)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536810000036
Popis: In the title compound, [Zn(NCS)(C12H18N2O2)2]NO3, the ZnII ion is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands and is also coordinated by the N atom of a thiocyanate ligand, giving a distorted trigonal-bipyramidal geometry. Intramolecular N—H...O hydrogen bonds are observed in the complex cation. The nitrate anions are linked to the complex cations through N—H...O hydrogen bonds.
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