Appearance of itinerant electrons detected by IR spectroscopy and its correlation with surface magnetism in Co-doped TiO2 nanopowders

Autor: Mostovshchikova E.V., Yermakov A.Ye., Uimin M.A., Minin A.S.
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: EPJ Web of Conferences, Vol 185, p 03006 (2018)
Druh dokumentu: article
ISSN: 2100-014X
DOI: 10.1051/epjconf/201818503006
Popis: IR absorption and magnetic data for the titanium dioxide nanopowders are studied. Additional absorption in IR range is revealed in nanocrystalline TiO2 and Co-doped TiO2 after reducing annealing and explained by appearance of the oxygen vacancies and delocalised charge carriers. Increasing of the absorption in IR range after annealing of Co-doped TiO2 in vacuum (or decreasing of this contribution after annealing in air) correlates with arising (or vanishing) of ferromagnetic contribution.
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