| Autor: |
Christine A. Bange, Neil T. Mucha, Morgan E. Cousins, Abigail C. Gehsmann, Anna Singer, Taylor Truax, Lee J. Higham, Rory Waterman |
| Jazyk: |
angličtina |
| Rok vydání: |
2016 |
| Předmět: |
|
| Zdroj: |
Inorganics, Vol 4, Iss 3, p 26 (2016) |
| Druh dokumentu: |
article |
| ISSN: |
2304-6740 |
| DOI: |
10.3390/inorganics4030026 |
| Popis: |
Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine 8-[(4-phosphino)phenyl]-4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene furnishes fluorescent phosphine products. Hydrophosphination of the fluorescent phosphine produces products with a complete selectivity for the secondary product. A key intermediate in catalysis, a zirconium phosphido compound, was isolated. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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