Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift

Autor: Yinghua Yu, Pushkin Chakraborty, Jinshuai Song, Lei Zhu, Chunsen Li, Xueliang Huang
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Nature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-019-14101-5
Popis: Transannular construction of medium-sized lactones is entropically unfavoured. Herein, the authors describe a strategy for valuable medium-sized lactone synthesis from available benzaldehydes by selective C-H bond functionalization via palladium carbene migratory insertion-enabled 1,4-palladium shift.
Databáze: Directory of Open Access Journals