Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining H2O Molecules

Autor:	Elí Sánchez-González, J. Gabriel Flores, Julio C. Flores-Reyes, Ivette Morales-Salazar, Roberto E. Blanco-Carapia, Mónica A. Rincón-Guevara, Alejandro Islas-Jácome, Eduardo González-Zamora, Julia Aguilar-Pliego, Ilich A. Ibarra
Jazyk:	angličtina
Rok vydání:	2020
Předmět:	MOFs structure transformation PXRD Le Bail refinements Technology Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
Zdroj:	Materials, Vol 13, Iss 8, p 1840 (2020)
Druh dokumentu:	article
ISSN:	1996-1944
DOI:	10.3390/ma13081840
Popis:	The structure transformation of Mg-CUK-1 due to the confinement of H2O molecules was investigated. Powder X-ray diffraction (PXRD) patterns were collected at different H2O loadings and the cell parameters of the H2O-loaded Mg-CUK-1 material were determined by the Le Bail strategy refinements. A bottleneck effect was observed when one hydrogen-bonded H2O molecule per unit cell (18% relative humidity (RH)) was confined within Mg-CUK-1, confirming the increase in the CO2 capture for Mg-CUK-1.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/6b6cdba7b7184b74b42eecc4ba975900 Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
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