Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry

Autor: Jiří Kulhánek, Filip Bureš, Miroslav Ludwig
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Beilstein Journal of Organic Chemistry, Vol 5, Iss 1, p 11 (2009)
Druh dokumentu: article
ISSN: 1860-5397
17028744
DOI: 10.3762/bjoc.5.11
Popis: Simple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki–Miyaura or Sonogashira coupling reactions.
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