Catalytically Active Imine-based Covalent Organic Frameworks for Detoxification of Nerve Agent Simulants in Aqueous Media

Autor:	Sergio Royuela, Rodrigo Gil-San Millán, María J. Mancheño, M. Mar Ramos, José L. Segura, Jorge A. R. Navarro, Félix Zamora
Jazyk:	angličtina
Rok vydání:	2019
Předmět:	covalent organic frameworks catalysis chemical warfare agents detoxification Technology Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
Zdroj:	Materials, Vol 12, Iss 12, p 1974 (2019)
Druh dokumentu:	article
ISSN:	1996-1944
DOI:	10.3390/ma12121974
Popis:	A series of imine-based covalent organic frameworks decorated in their cavities with different alkynyl, pyrrolidine, and N-methylpyrrolidine functional groups have been synthetized. These materials exhibit catalytic activity in aqueous media for the hydrolytic detoxification of nerve agents, as exemplified with nerve gas simulant diisopropylfluorophosphate (DIFP). These preliminary results suggest imine-based covalent organic frameworks (COFs) as promising materials for detoxification of highly toxic molecules.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/a6b0e4c892214048a3f20b18c72a0bee Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
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