Autor: |
Guangpeng Jiang, Yuheng Ma, Sihua Zhang, Rulin Chen, Zhe Li, Jun Li, Ruiqian Li, Dongliang Tao |
Jazyk: |
angličtina |
Rok vydání: |
2023 |
Předmět: |
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Zdroj: |
Materials & Design, Vol 233, Iss , Pp 112300- (2023) |
Druh dokumentu: |
article |
ISSN: |
0264-1275 |
DOI: |
10.1016/j.matdes.2023.112300 |
Popis: |
Synthesizing lanthanide complexes and their hybrid materials often involves the utilization of hazard base reagents to neutralize the protons generated in coordination reactions. Here, we propose for the first time a green and facile route to synthesize europium-complex-based hybrid materials by using micrometer-sized hydroxyapatite (HAP). Simultaneous formations of the europium complex and monetite took place after the reaction. Not only did HAP function as an eco-friendly alkaline reagent, but it also acted as a matrix to disperse the europium complexes. The quantum yield and lifetime of the as-synthesized hybrid materials are comparable to that of pure europium complex prepared by using traditional base reagents. Furthermore, versatile applications of the hybrid materials are also demonstrated in our proof-of-concept experiments, including bone tissue engineering, luminescent toys, and portable luminescent chalks. Notably, the proposed eco-friendly strategy is also applicable to other types of lanthanide-complexes-based hybrid materials. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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