2,5-Bis{[(–)-(S)-1-(4-methylphenyl)ethyl]iminomethyl}thiophene
| Autor: | Sylvain Bernès, Guadalupe Hernández-Téllez, Manju Sharma, Oscar Portillo-Moreno, René Gutiérrez |
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| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 69, Iss 9, Pp o1428-o1428 (2013) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536813021685 |
| Popis: | The title chiral bis-aldimine, C24H26N2S, was synthesized using a solvent-free Schiff condensation. The molecule displays crystallographic C2 symmetry, with the S atom lying on the twofold axis parallel to [100]. As a consequence of the (S,S) stereochemistry, the tolyl groups are oriented towards opposite faces of the thiophene core, giving a twisted conformation for the whole molecule. Molecules are arranged in the crystal in a herringbone-like pattern, without any significant intermolecular contacts. |
| Databáze: | Directory of Open Access Journals |
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