Hydrosulfide-selective ChemFETs for aqueous H2S/HS− measurement

Autor: Tobias J. Sherbow, Grace M. Kuhl, Grace A. Lindquist, Jordan D. Levine, Michael D. Pluth, Darren W. Johnson, Sean A. Fontenot
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Sensing and Bio-Sensing Research, Vol 31, Iss , Pp 100394- (2021)
Druh dokumentu: article
ISSN: 2214-1804
DOI: 10.1016/j.sbsr.2020.100394
Popis: We have prepared and characterized hydrosulfide-selective ChemFET devices based on a nitrile butadiene rubber membrane containing tetraoctylammonium nitrate as a chemical recognition element that is applied to commercially available field-effect transistors. The sensors have fast (120 s) reversible responses, selectivity over other biologically relevant thiol-containing species, detection limits of 8 mM, and a detection range from approximately 5 to 500 mM. Sensitivities are shown to be 53 mV per decade at pH 8. Use of this compact, benchtop sensor platform requires little training – only the ability to measure DC voltage, which can be accomplished with a conventional multimeter or a simple analog data acquisition device paired with a personal computer. To the best of our knowledge, this report describes the first example of direct potentiometric measurement of the hydrosulfide ion in water.
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