| Autor: |
P. Kalaivani, F. Dallemer, R. Prabhakaran |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
Chemistry of Inorganic Materials, Vol 3, Iss , Pp 100057- (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2949-7469 |
| DOI: |
10.1016/j.cinorg.2024.100057 |
| Popis: |
Reaction between 2-hydroxy-1-naphthaldehyde thiosemicarbazone and square planar dichloro bis triphenylphosphine Cu(II) resulted in two structurally different binuclear Cu(I) tetrahedral complexes which are co-crystallized together by exhibiting bonding isomerism. The reaction of co-crystallized complexes with [NiCl2(PPh3)2] led to C–S and Cu–S activation of coordinated ligand to form [Cu2(μ2-Cl2)(PPh3)3] and [Cu2(μ2-S2)(PPh3)3] respectively along with a square planar [Ni(nap-tsc)(PPh3)] (where, nap-tsc =2-hydroxy-1-naphthaldehyde thiosemicarbazone) and triphenylphosphine sulfide. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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