Tetra-μ-acetato-κ8O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN1]copper(II)}
| Autor: | Zainal A. Fairuz, Zaharah Aiyub, Zanariah Abdullah, Seik Weng Ng, Edward R. T. Tiekink |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 9, Pp m1049-m1050 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810030187 |
| Popis: | In the crystal structure of the title complex, [Cu2(CH3COO)4(C12H11ClN2)2], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of CuII atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)°. An intramolecular N—H...O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C—H...π type link molecules in the crystal structure. |
| Databáze: | Directory of Open Access Journals |
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