Percolation phenomena in the polymer composites with conducting polymer fillers

Autor: G.V. Martyniuk, O.I. Aksimentyeva
Jazyk: English<br />Ukrainian
Rok vydání: 2021
Předmět:
Zdroj: Фізика і хімія твердого тіла, Vol 22, Iss 4, Pp 811-816 (2021)
Druh dokumentu: article
ISSN: 1729-4428
2309-8589
DOI: 10.15330/pcss.22.4.811-816
Popis: The electrical properties of polymer nanocomposites based on dielectric polymer matrices of different types and electrically conductive polymer fillers – polyortotoluidine, polyorthoanisidine and polyaniline have been studied. It is shown that the concentration dependence of the specific conductivity on the content of fillers has a percolation character with a low “percolation threshold”, which depends on the nature of the polymer matrix and polyaminoarene and is 1.7-10.0 vol.%. The calculated critical parameters of electroconductivity are characteristic of the formation of an infinite 3-dimensional cluster of conductivity and indicate a significant influence of the nature of the components and morphology of the material on the charge transfer processes in such systems.
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