Poly[[μ2-aqua-aqua(μ3-3,5-dinitrosalicylato)barium(II)] monohydrate]
| Autor: | Xiao-Min Hao, Chang-Sheng Gu, Run-Zhen Fan, Wen-Dong Song |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 4, Pp m551-m551 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808006338 |
| Popis: | In the title coordination polymer, {[Ba(C7H2N2O7)(H2O)2]·H2O}n, the BaII atom is ten-coordinated by seven O atoms from four 3,5-dinitrosalicylatate ligands, two μ2-bridging aqua ligands and one water molecule. The coordination mode is best described as a bicapped square-antiprismatic geometry. The 3,5-dinitrosalicylatate ligands bridge three Ba atoms. Centrosymmetrically related dinuclear barium units, with a Ba...Ba separation of 4.767 (5) Å, form infinite chains, which are further self-assembled into a supramolecular network through intermolecular O—H...O hydrogen-bonding interactions between O atoms of 3,5-dinitrosalicylatate ligands and water molecules. |
| Databáze: | Directory of Open Access Journals |
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