Effective one-pot synthesis of (E)-poly(vinyl arylenes) via trans-borylation/Suzuki coupling protocol

Autor:	Szyling Jakub, Walkowiak Jędrzej
Jazyk:	angličtina
Rok vydání:	2017
Předmět:	one-pot synthesis organoboron derivatives poly(arylene vinylene) suzuki coupling trans-borylation Chemistry QD1-999
Zdroj:	Green Processing and Synthesis, Vol 6, Iss 3, Pp 301-310 (2017)
Druh dokumentu:	article
ISSN:	2191-9542 2191-9550
DOI:	10.1515/gps-2016-0217
Popis:	A new stereoselective method for the synthesis of (E)-poly(vinylarenes) on the basis of the Ru-H catalyzed trans-borylation reaction and sequential Suzuki coupling is described. Two different strategies of Pd-catalyzed polycondensation leading to unsaturated organic macromolecular compounds are discussed. Development of a one-pot procedure reduces costs and time, needed for the separation of intermediates, the amount of organic solvents used for purification and therefore has a positive influence on the process sustainability.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/695d8941c4da4eb9b33d179c33f9d958 Zobrazit plný text záznamu View record in DOAJ