4-Azafluorenone and α-Carboline Fluorophores with Green and Violet/Blue Emission

Autor: Marek Cigáň, Peter Danko, Henrich Brath, Matúš Čakurda, Roman Fišera, Jana Donovalová, Juraj Filo, Martin Weis, Ján Jakabovič, Miroslav Novota, Anton Gáplovský
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Molecules, Vol 24, Iss 13, p 2378 (2019)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/molecules24132378
Popis: The emission properties of three 4-azafluorenone and five new α-carboline fluorophores in both solution and thin solid films were investigated. Fluorescence of the azafluorenone is clearly enhanced in thin solid films due to the presence of phenyl/biphenyl rotors, and these derivatives can be classified as green Aggregation-Induced Emission luminogens (AIEgens) with a non-emissive heteroaromatic core structure. Compared to azafluorenones, emission of α-carbolines is hypsochromically shifted to the blue region of the electromagnetic spectrum, and most of these derivatives exhibit strong violet-blue fluorescence in both solution and thin solid film layers. Further, the effective mobility and electroluminescence of new α-carbolines were investigated in prepared organic field-effect transistors and organic light-emitting diodes, respectively.
Databáze: Directory of Open Access Journals
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