Application of Magnetic Separation in Catalyst Reuse Applied in Paracetamol Degradation

Autor: Jessica R. P. Oliveira, Eduardo Abreu, Maria E. K. Fuziki, Elaine T. de Paula, Michel Z. Fidelis, Rodrigo Brackmann, Angelo M. Tusset, Odivaldo C. Alves, Giane G. Lenzi
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Magnetism, Vol 4, Iss 3, Pp 240-251 (2024)
Druh dokumentu: article
ISSN: 2673-8724
DOI: 10.3390/magnetism4030016
Popis: This work presents an investigation of the degradation of paracetamol via heterogeneous photocatalysis, aiming to magnetically immobilize the catalyst in a continuous process. Catalyst immobilization was conducted on aggregated flower-like structures. The CoFe2O4@Nb5O2 catalyst was characterized using a Vibrating Sample Magnetometer (VSM). The effects of the magnetic immobilization of the catalyst, flow, residence time, adsorption, and photolysis were evaluated. Additionally, catalyst reuse cycles were analyzed. The results indicated that a longer residence time favors the degradation of paracetamol due to the increase in the contact time of the effluent catalyst. At a flow rate of 20 mL·min−1, a degradation of 27% was obtained. Photolysis and adsorption tests indicated that residence time was not an important factor for paracetamol degradation. For the photolysis test, in the first cycle, the values obtained were in the range of 6.0–8.5%. The adsorption results indicated ~10% removal.
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