Bulk Hyperpolarization of Inorganic Materials

Autor:	Snædís Björgvinsdóttir, Lyndon Emsley
Jazyk:	German<br />English<br />French
Rok vydání:	2021
Předmět:	dynamic nuclear polarization inorganic materials nuclear magnetic resonance spin diffusion Chemistry QD1-999
Zdroj:	CHIMIA, Vol 75, Iss 4, Pp 333-337 (2021)
Druh dokumentu:	article
ISSN:	0009-4293 2673-2424
DOI:	10.2533/chimia.2021.333
Popis:	Solid-state NMR spectroscopy is a well-established method to obtain atomic-level information about the structure of inorganic materials, but its use is often limited by low sensitivity. We review how solvent generated dynamic nuclear polarization can be used to increase sensitivity in solid-state NMR of inorganic materials, with emphasis on our recent method for hyperpolarization of proton-free bulk. We use selected examples to show how overall gains in sensitivity can be observed in both the surface and bulk spectra of inorganic compounds such as lithium titanate. The hyperpolarization methods reviewed here can be used to improve NMR sensitivity for a range of inorganic materials.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/68570c19669b469a8abba85db08dc3a2 Zobrazit plný text záznamu View record in DOAJ