Rhodanine-Bridged Core-Expanded Naphthalene Diimide Derivatives for n-Type Semiconductors

Autor: Jiangao Li, Jing Li, Congwu Ge, Xike Gao
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Organic Materials, Vol 02, Iss 02, Pp 165-172 (2020)
Druh dokumentu: article
ISSN: 2625-1825
DOI: 10.1055/s-0040-1710550
Popis: Abstract The core expansion of naphthalene diimides (NDIs) is an effective strategy to modulate frontier molecular orbital energy levels and improve device performances. Herein two new rhodanine-bridged and core-extended NDIs T1 and T2 were designed and synthesized. The rhodanine moiety could act not only as a π-spacer to enlarge the molecular conjugated system, but also as an electron-donating unit to tune the molecular energy levels. As a result, both T1 and T2 showed slightly lower lying LUMO energy levels (
Databáze: Directory of Open Access Journals