trans-{1,8-Bis[(S)-1-phenylethyl]-1,3,6,8,10,13-hexaazacyclotetradecane}bis(thiocyanato-κN)copper(II)
| Autor: | Jong Won Shin, Sankara Rao Rowthu, Jae Jeong Ryoo, Kil Sik Min |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 8, Pp m919-m920 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810026632 |
| Popis: | In the title thiocyanate-coordinated aza-macrocyclic copper(II) complex, [Cu(NCS)2(C24H38N6)], the CuII atom is coordinated by the four secondary N atoms of the aza-macrocyclic ligand and by the two N atoms of the thiocyanate ions in a tetragonally distorted octahedral geometry. The average equatorial Cu—N bond length is shorter than the average axial Cu—N bond length [2.010 (2) and 2.528 (4) Å, respectively]. An N—H...N hydrogen-bonding interaction between the secondary amine N atom and the adjacent thiocyanate ion leads to a polymeric chain along the a axis. |
| Databáze: | Directory of Open Access Journals |
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