| Autor: |
VUKADIN M. LEOVAC, ZORAN D. TOMIC, KATALIN MÉSZÁROS SZÉCSÉNYI, LJILJANA S. JOVANOVIC, MILAN D. JOKSOVIC |
| Jazyk: |
angličtina |
| Rok vydání: |
2007 |
| Předmět: |
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| Zdroj: |
Journal of the Serbian Chemical Society, Vol 72, Iss 12, Pp 1281-1293 (2007) |
| Druh dokumentu: |
article |
| ISSN: |
0352-5139 |
| Popis: |
The crystal and molecular structures of four tetrahedral structurally similar [Co(aamp)2X2] complexes (aamp = 4-acetyl-3-amino-5-methylpyrazole, X = Cl, Br, I and NCS) were determined by X-ray diffraction analysis and are discussed in detail. It was found that the different capacity of the ligand X (NCS vs. Cl, Br, I) for the formation of non-bonding cntacts influence the mode of molecular association in the solid state. The complexes were characterized by UV–Vis spectroscopy. The first step of the thermal decomposition of the compounds was checked and is discussed in the view of the IR spectrum of the intermediate isolated from [Co(aamp)2Br2] by the quasi-isothermal technique. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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