Autor: |
Erli Lu, Saira Sajjad, Victoria E. J. Berryman, Ashley J. Wooles, Nikolas Kaltsoyannis, Stephen T. Liddle |
Jazyk: |
angličtina |
Rok vydání: |
2019 |
Předmět: |
|
Zdroj: |
Nature Communications, Vol 10, Iss 1, Pp 1-10 (2019) |
Druh dokumentu: |
article |
ISSN: |
2041-1723 |
DOI: |
10.1038/s41467-019-08553-y |
Popis: |
In actinide chemistry, a longstanding bonding model describes metal-ligand binding using 6d-orbitals, with the 5f-orbitals remaining non-bonding. Here the authors explore the inverse-trans-influence — a case where the model breaks down — finding that the f-orbitals play a crucial role in dictating a trans-ligand-directed geometry. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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