Copper conductive patterns through spray-pyrolysis of copper-diethanolamine complex solution.

Autor: Jutamart Chotipanich, Suraya Hanim Abu Bakar, Amornchai Arponwichanop, Tetsu Yonezawa, Soorathep Kheawhom
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: PLoS ONE, Vol 13, Iss 7, p e0200084 (2018)
Druh dokumentu: article
ISSN: 1932-6203
DOI: 10.1371/journal.pone.0200084
Popis: A simple and low-cost method to fabricate copper conductive patterns at low temperature is critical for printed electronics. Low-temperature spray-pyrolysis of copper-alkanolamine complex solution shows high potential for this application. However, the produced copper patterns exhibit a granular structure consisting of connected fine copper particles. In this work, low-temperature spray-pyrolysis of copper formate-diethanolamine complex solution under N2 flow at a temperature of 200 °C was investigated. The effects of spraying conditions on microstructure and electrical properties of the patterns were examined. Our results revealed that the spraying rate is a critical parameter determining the degree of sintering and electrical resistivity of the patterns. A low spraying rate facilitates sintering, and hence well-sintered copper patterns with the lowest resistivity of 6.12 μΩ.cm (3.6 times of bulk copper) on a polyimide substrate could be fabricated.
Databáze: Directory of Open Access Journals
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