Elucidating the Structural Features of Bis(arylimino)acenaphthene (Aryl-BIAN) Bismuth Complexes: A Combined Single-Crystal X-ray Diffraction and Hirshfeld Analysis Approach

Autor:	Beatriz P. Machado, Maria Celador-Garcia, Vitor Rosa, Clara S. B. Gomes
Jazyk:	angličtina
Rok vydání:	2024
Předmět:	bismuth bis(arylimino)acenaphthene (Aryl-BIAN) ligands X-ray structure Hirshfeld surface analysis Inorganic chemistry QD146-197
Zdroj:	Inorganics, Vol 12, Iss 5, p 135 (2024)
Druh dokumentu:	article
ISSN:	2304-6740
DOI:	10.3390/inorganics12050135
Popis:	Dimeric bismuth(III) complexes bearing bis(aryl-imino)acenaphthene (Aryl-BIAN) donor ligands of the general formulae [(Dipp-BIAN)BiCl3]2 2, [(o-iPr-BIAN)BiCl3]2 3, and [(p-iPr-BIAN)BiCl3]2 4, where Dipp = diisopropyl, o-iPr = ortho-isopropyl and p-iPr = para-isopropyl, were prepared by reaction of the corresponding neutral BIAN ligand with BiCl3, under inert atmosphere conditions. X-ray studies were performed, and their molecular structures were determined. The individual contributions of intermolecular interactions to crystal packing have been quantified by means of Hirsfeld surface analysis.
Databáze:	Directory of Open Access Journals
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