Tris(2,2′-bipyridine)copper(II) pentacyanidonitrosoferrate(II) methanol disolvate monohydrate
| Autor: | Julia A. Rusanova, Oksana V. Nesterova, Roman I. Zubatyuk, Olesia V. Kozachuk |
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| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 69, Iss 4, Pp m212-m213 (2013) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536813006867 |
| Popis: | The title complex [Cu(C10H8N2)3][Fe(CN)5(NO)]·2CH3OH·H2O, consists of discrete [Cu(bpy)3]2+ cations (bpy is 2,2′-bipyridine), [Fe(CN)5NO]2− anions and solvent molecules of crystallization (two methanol molecules and one water molecules per asymmetric unit). The CuII ion adopts a distorted octahedral environment, coordinated by six N atoms from three bpy ligands. The cation charge is balanced by a nitroprusside counter-anion, which has a slightly distorted octahedral coordination geometry. In the crystal, anions and solvent molecules are involved in O—H...N and O—H...O hydrogen bonds, which form chains along [100]. The cations are located between these chains. |
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