| Autor: |
Eisuke SATO, Sayaka OGITA, Koichi MITSUDO, Seiji SUGA |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
|
| Zdroj: |
Electrochemistry, Vol 91, Iss 11, Pp 112005-112005 (2023) |
| Druh dokumentu: |
article |
| ISSN: |
2186-2451 |
| DOI: |
10.5796/electrochemistry.23-67079 |
| Popis: |
Cathodic reduction efficiently cleaved N–O bonds. The simple cathodic reduction of Weinreb amides in a divided cell afforded the corresponding amide in good yields. Cyclic voltammetry experiments and density functional theory calculations suggested that the direct reduction of the N-methoxy amide generates the methoxy radical and amide anion. The release of methanol derived from methoxy radical would be the driving force of the N–O bond cleavage. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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