Synthesis and Thermotropic Phase Behavior of Four Glycoglycerolipids

Autor:	Marité Cárdenas, Christian M. Pedersen, Vivien Jagalski, Mikael Bols, Thomas G. Pomorski, Wouter F. J. Hogendorf
Jazyk:	angličtina
Rok vydání:	2013
Předmět:	glycolipid synthesis calorimetrics biomimetic membranes physiological conditions Organic chemistry QD241-441
Zdroj:	Molecules, Vol 18, Iss 11, Pp 13546-13573 (2013)
Druh dokumentu:	article
ISSN:	1420-3049 66536812
DOI:	10.3390/molecules181113546
Popis:	Four glycoglycerolipids with different head groups have been synthesized and their physicochemical properties studied. The lengths of the head groups from a mono-saccharide to a trisaccharide, in addition to the anomeric stereochemistry for the smaller glycoglycerolipids, have been modified. The synthesis has been optimized to avoid glycerol epimerization and to allow up-scaling. The physicochemical properties of the glycoglycerolipids were studied and a strong de-mixing of the gel-phase, depending on the head-group, was observed.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/a6653681256442aeb543259fd2f5e8e6 Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF