Effect of Coordinating Solvents on the Structure of Cu(II)-4,4′-bipyridine Coordination Polymers

Autor:	Marzio Rancan, Alice Carlotto, Gregorio Bottaro, Lidia Armelao
Jazyk:	angličtina
Rok vydání:	2019
Předmět:	coordination polymer MOF CP dimensionality control Cu(II)-4 4′-bipyridine dipyridil ligand copper Inorganic chemistry QD146-197
Zdroj:	Inorganics, Vol 7, Iss 8, p 103 (2019)
Druh dokumentu:	article
ISSN:	2304-6740
DOI:	10.3390/inorganics7080103
Popis:	Solvent can play a crucial role in the synthesis of coordination polymers (CPs). Here, this study reports how the coordinating solvent approach (CSA) can be used as an effective tool to control the nature of the final CP. This study exploited the system Cu(II)-4,4′-bipyridine coupled to different coordinating solvents, such as DMA, DMF and DMSO. This allowed the isolation and structurally characterization of four new CPs: three 2D layered networks and one 1D chain. Moreover, it was evidenced that even adventitious water can play the role of the coordinating solvent in the final CP.
Databáze:	Directory of Open Access Journals
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