Boundary Lubricant Film Properties versus Molecular Polarity of Perfluoropolyethers Containing a Pendant Chain

Autor: Robert J. Waltman, Hong Deng, Yu-Chen Wu, Hiroyuki Matsumoto
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: Tribology Online, Vol 7, Iss 1, Pp 41-45 (2012)
Druh dokumentu: article
ISSN: 1881-2198
DOI: 10.2474/trol.7.41
Popis: The thin film properties of some novel branched perfluoropolyether (PFPE) boundary lubricants are investigated as a function of molecular polarity and end-group bonding to the underlying carbon film. The PFPE main chain, comprised of n-perfluoroethylene oxide monomer units, is stiffer than the Fomblin Z main chain that is a copolymer of perfluoro-methylene oxide and -ethylene oxide monomer units. Terraced flow and bonding kinetics show decreased lubricant mobility compared to PFPEs based on a Fomblin Z main chain. Lubricant pick-up is reduced for the tetraol adduct due to the larger Hamaker constant and increased intermolecular cohesion.
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